Detailed Explanation:

Surya Sen, also known as Master Da, led the famous Chittagong Armoury Raid on 18 April 1930. He commanded a group of revolutionaries who raided the armoury and auxiliary forces magazine, temporarily capturing Chittagong and hoisting the national flag.

Rash Behari Bose was involved in the Delhi-Lahore Conspiracy and later fled to Japan, Chandra Shekhar Azad led the Hindustan Socialist Republican Association, and Batukeshwar Dutt participated in the Assembly Bombing case with Bhagat Singh—none were associated with the Chittagong Raid.

Therefore, Surya Sen's direct leadership of the Chittagong Armoury Raid makes Option 4 the correct answer.